PROPIEDADES QUIMICAS DE LOS ALCOHOLES

OXIDACION : la oxidacion es la reacción de alcoholes para producir ácidos carboxilicos, cetonas o aldehídos dependiendo de el tipo de alcohol y de catalizador, puede ser:
  • La reacción de un alcohol primario con  ácido crómico (CrO3) en presencia de piridina produce un aldehído:


  • la reacción de un alcohol primario en presencia del reactivo de jones produce un ácido carboxilo:
  • la reacción de un alcohol secundario en presencia de permanganato de potasio produce una cetona:


 DESHIDROGENACION: Los alcoholes primarios y secundarios cuando se calientan en contacto con ciertos catalizadores, pierden átomos de hidrógeno para formar aldehídos o cetonas. Si esta deshidrogenación se realiza en presencia de aire (O) el hidrógeno sobrante se combina con el oxígeno para dar agua.

 HALOGENACION: el alcohol reacciona con el ácido hidrácido para formar haluros de alquilo mas agua:
R-OH  +  HX -------------------)    R-X   + H2O

DESHIDRATACION: es una propiedad de los alcoholes mediante la cual podemos obtener eteres o alquenos:
2 R -CH2OH  ----------------)  R - CH2 - O - CH2 - R'

R-R-OH ------------)  R=R   + H2O

REACCION CON CLORURO DE TIONILO:
El cloruro de tionilo (SOCl2) se puede usar para convertir alcoholes en el correspondiente cloruro de alquilo en una reacción simple que produce HCl gaseoso y SO2.






148 comentarios:

Unknown dijo...

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midori dijo...

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Unknown dijo...

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Unknown dijo...

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Anónimo dijo...

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Unknown dijo...

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Juan Marriaga M. dijo...

oxido-reduccion buen trabajo

Unknown dijo...

Muy bueno

alan1298 dijo...

las propiedades de los alcoholes son las reacciones de este?

Unknown dijo...

Neta te estas rifando, ya tengo la tarea hecha, vales mil

Unknown dijo...

muy buena info gracias!!

DDT dijo...

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Unknown dijo...

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